methyl benzoate safety precautions

Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. Remove the cold bath and let the mixture stand at room temperature for 20 minutes, with continuous stirring. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. A Synonyms: Dyzana Paintball Pants, Methyl benzoate is an organic compound. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. Link to the EU Cosmetic Regulation: http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, Find out more about the regulation of Food Additives by the Food and Drug Administration, Food Ingredients and Packaging: http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, Food Contact Substances: http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, Substances Generally Recognized As Safe (GRAS): http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, Search the Code of Federal Regulations http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, EU Cosmetics Inventory http://ec.europa.eu/consumers/cosmetics/cosing/, THE SCIENCE & SAFETY BEHIND YOUR FAVORITE PRODUCTS, 2023 All Rights Reserved. Uses advised against Food, drug, pesticide or biocidal product use. PB85141216. Remove contaminated clothes. Electron-withdrawing groups have a deactivating effect on the ring. Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Nicotine is a naturally produced alkaloid in the nightshade family of plants (most predominantly in tobacco and Duboisia hopwoodii) and is widely used recreationally as a stimulant and anxiolytic.As a pharmaceutical drug, it is used for smoking cessation to relieve withdrawal symptoms. Do not induce vomiting. SAFETY DATA SHEET Version 5.2 Revision Date 04/02/2015 Print Date 12/20/2016 1. %%EOF Refer to Health & Safety and Technical notes section below for additional information. Keep patient quiet and maintain normal body temperature. tract irritation. endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream 0000006427 00000 n endobj Warning. Sodium benzoate 25 mg. Propylene glycol 2.72 mg. For the full list of excipients, see section 6.1. stemmed pipet, over 3-4 minutes, to the methyl benzoate/sulfuric acid solution, which should still be kept cold in the ice bath and being continuously stirred. A crystalline solid or a solid dissolved in a liquid. >> 0000003105 00000 n 0000017719 00000 n Koc values for the Podzol, Alfisol and sediment were 178, 103, and 95, respectively(1). Methyl benzoate is formed by the condensation of methanol and benzoic acid, in presence of a strong acid such as hydrochloric acid . ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. Using a structure estimation method based on molecular connectivity indices(3), the Koc of methyl benzoate can be estimated to be 70(SRC). Slightly soluble in water. P301+P317 IF SWALLOWED: Get medical help. [Beilstein 9 IV 283.]. Material Safety Data Sheet Version 4.2 Revision Date 06/14/2011 Print Date 08/26/2011 1. The nitration of methyl benzoate is an example of electrophilic substitution. Diazomethane is the chemical compound CH 2 N 2, discovered by German chemist Hans von Pechmann in 1894. Do not discharge to sewer systems. 1 Reagent Lane The safety of Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate has been assessed by the Cosmetic Ingredient Review (CIR) Expert Panel. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. It is a benzoate ester and a methyl ester. Read our standard health & safety guidance. 1. Heat is also generated by the interaction of esters with caustic solutions. Keep in suitable, closed containers for disposal. Wash the crude product with a little ice-cold water. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. endobj 0000008079 00000 n Cool the nitric acid by partially immersing it in an ice-water bath before slowly adding, with swirling, 1.5 cm3 of concentrated sulfuric acid. 0000000016 00000 n The term "iso" in the name means that the carbon chain of the alcohol is branched. The ester group attached to the benzene ring of methyl benzoate. Copyright 2022 ChemicalBook. 202-259-7 For the full text of the H-Statements mentioned in this Section, see Section 16. . Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. Methyl benzoate is an ester. When heated to decomposition it emits f Inhaling Methyl Benzoate can irritate the nose, throat and lungs. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. May be harmful if It is also used for cellulose esters, cellulose ethers, synthetic resin and rubber solvent and polyester fibers to assist in the preparation of flavor. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Tabulated list of adverse reactions. 0000017521 00000 n Methyl benzoate reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. f Repeated exposure to high levels may affect the nervous system. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Synthesise and recrystallize a sample of methyl 3-nitrobenzoate. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Precautionary Statements. : 93-58-3 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against . "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! Ensure adequate ventilation. This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. 1 0 obj Precautions for Scalp and Hair Treatment: Avoid contact with the eyes. Hazard Statements. ethanol (FLAMMABLE highly flammable liquid and vapour). Nitration is an important step in synthesis, including the manufacture of explosives and formation of amines. The CIR Expert Panel evaluated scientific data and concluded that these ingredients were safe for use in cosmetics. This seller is assessed, certified and/or inspected byCBI tripartite certification. DOSAGE AND ADMINISTRATION. Your Trusted Stop To Buy The Best Mint Products. This should be carried out on an electric hot plate to avoid naked flames. Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. Mildly toxic by skin contact. An estimated BCF of 12 was calculated in fish for methyl benzoate(SRC), using a log Kow of 2.12(1) and a regression-derived equation(2). endobj (For reference only, please check.). The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. Ethyl hydroxybenzoate (E214) 5mg/5ml. Set up emergency exits and the risk-elimination area. This supplier was in ECHEMIs Top 10 Suppliers list last year. Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. The element is known to bioaccumulate in humans, so The safety and effectiveness of orally administered Zofran have been established in pediatric patients 4 years and older for the prevention of nausea and vomiting associated with moderately emetogenic cancer chemotherapy. Normally stable, even under fire conditions. %PDF-1.4 % iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. Symptoms of overdose. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 These side effects may go away during treatment as your body adjusts to the medicine. Do you expect ortho-, meta-, or para-nitration? receptor type. The reaction is regioselective and produces predominantly methyl 3-nitrobenzoate. Methyl benzoate | C6H5COOCH3 - PubChem Apologies, we are having some trouble retrieving data from our servers. SODIUM BISULFATE. Thermacell Radius Zone Mosquito Repellent, It does not represent any guarantee of the properties of the product. 0000003603 00000 n Tel: +968-2250 7015 Phenytoin (PHT), sold under the brand name Dilantin among others, is an anti-seizure medication. Procedure: For the best results, dosage should start at the first sign of an attack.Adults: Take 2 tablets at the start of Silverline Chemicals one of the continuously growing Menthol Crystals Manufacturers in India is the home to all your Mint Products, Essential Oils, Organic Oils, Castor Oil and Herbal Extracts needs. GHS07. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". 0 If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. f Methyl Benzoate can affect you when inhaled and may be absorbed through the skin. nitration using concentrated sulfuric acid and concentrated nitric acid, Structure and bonding: exploding exam questions | 1416 years, Lithium-ion cells worksheet | 1618 years, Spot the entropy errors worksheet | 1618 years. ), IATA: Not dangerous goods. It is functionally related to a gamma-aminobutyric acid. c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. 0000005585 00000 n Use in a well ventilated area. This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. Methyl benzoate is an organic compound.It is an ester with the chemical formula C 6 H 5 CO 2 CH 3.It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents.Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Methyl benzoate is included in Herbicides category. Students should be able to outline the electrophilic substitution mechanism of: nitration (including the generation of the nitronium ion). Therefore the reaction is regioselective for nitration at the 3-position. 0000017078 00000 n Causes redness and pain. PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For 4 0 obj 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 01 Revision Date: 02-02-2015 Print Date: 11-26-2015 Page 1 of 10 1. Wash . 0000002359 00000 n e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. <> For CHEMTREC assistance, call: 800-424-9300 2. May be harmful if inhaled. Hazard Statements. 6.1 Personal precautions . It also finds use as a solvent and as a pesticide used to attract The principal food safety incident in Taiwan was over the use of the plasticizer DEHP to replace palm oil in food and drinks as a clouding agent. CHEMICAL Do you expect ortho-, meta-, or para-nitration? Wash clothing before reuse. << SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . Benzoic acid, methyl ester; Oil of niobe. Esters react with acids to liberate heat along with alcohols and acids. It may also be used for Personal precautions, protective equipment and emergency procedures 6.1.1. Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. Immediately flush contaminated eyes with gently flowing water. Pictograms. In contrast to other PDE5 H302. It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study. Contact may slightly irritate skin, eyes and mucous membranes. Incompatible with strong acids, strong bases, nitrates, oxidizers. 0000001694 00000 n Combustible liquid (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. To fight fire, use Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone. Hazards and Precautions. Copyright 2019 Future Technologies LLC In this experiment the students nitrate methyl benzoate. It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. EYES: First check the victim for contact lenses and remove if present. : 5026-62- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. Special Hazards of Combustion Products: None (USCG, 1999). MSDS Name: Methyl Benzoate Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. <> Clorius; Essence of niobe; Benzoic acid,methyl ester. Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. 5!GJ3q"R5T0523"S@/% 2 mh:tR@0244F`PYb_MPz V$( q*87%8pYXTDYBZ LL !utIq AM~$*hSUyTT#maw5q8W7#7\ AQC%Fn4n4|9wA V:i>{&7}[wAl^6$bX)}|DZ)Q{Pmp?m`@ natural, 98%, FCC, FG. }zr;5If4 kR.:F R4;i%OTv*^W%U8j d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. It is naturally occurring in guava, mango, and kiwifruit. Used for treatment of neuropathic pain and restless legs syndrome. 26 34 Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. Yu7&*4}"/u :Sky6) Stable. Sunscreens: How to Read a Label, Expert Tips, etc. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product. It does not represent any guarantee of the properties of the product. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. SAFETY DATA SHEET Version 6.6 Revision Date 09/16/2021 Print Date 01/15/2023 . METHYL BENZOATE is an ester. These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. Members are provided with comprehensive ways to promote their products. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . . %PDF-1.6 % May cause allegic skin and respiratory reactions. The chemical name is (S)-6-methoxy--methyl-2-naphthalene acetic acid. Office of Response and Restoration, Heat is also generated by the interaction of esters with caustic solutions. This is a METHYL ETHYL KETONE (MEK) METHYL FORMATE. (USCG, 1999). Article 10. Look through Methyl3-(aminomethyl)benzoate MSDS details show. xSn0h VHzu^Z5S:i8F k H: b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 1 0 obj Use standard firefighting procedures and Consolidate learning about simple displacement reactions with this game, followed by a formative assessment activity for the whole class, Five steps to confidence for your post-16 learners, How chemistry provides oxygen for breathing in emergency situations, Present and prastice a technique to help learners understand the language used in extended-reponse questions and improve their answers, Review your learners understanding of electrochemistryand its applications, Develop your learners metacognitive skills using thermodynamics questions and calculations, The physics of restoration and conservation, RSC Yusuf Hamied Inspirational Science Programme, How to prepare for the Chemistry Olympiad, Nitration of methyl benzoate - student sheet, (c) mechanism of electrophilic substitution, such as in the nitration, halogenation and Friedel-Crafts alkylation of benzene, as the characteristic reaction of arenes, Unit A2 1: Further Physical and Organic Chemistry. Approved respirator, chemical safety goggles, chemical-resistant gloves. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. 59 0 obj <>stream Above 83C use a closed system and ventilation. Propyl hydroxybenzoate (E216) 4mg/5ml. Stir the crushed ice throughout. RXR\N g Allow the ice to melt and filter under suction. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely. 0000002518 00000 n Stir the reaction mixture as the addition is made. Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. b Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). Follow this link for more information about how preservatives protect cosmetics and personal care products. Ensure thorough mixing. Collect leaking and spilled liquid in sealable containers as far as possible. Precautionary Statements. Company Identification: What Is Wrong With Disney Adults. Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. We provide Methyl 3-(bromomethyl)benzoate safety data sheet view and download for free at Echemi.com. Scientific literature review of Benzyl alcohol, benzaldehyde, benzoic acid and related compounds. >> fire. Avoid contact with skin and eyes. Methyl benzoate is an organic compound. 0000008888 00000 n May cause allegic skin and respiratory reactions.Theacute oral toxicity in test animals was oflow order. /PageMode /UseNone The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. Metronidazole Benzoate Ph Eur 320mg/5ml. f Carefully pour the reaction mixture onto a small amount (approx. Avoid breathing vapors, mist or gas. The short chain alkyl benzoate ingredients were not dermal sensitizers. Ensure adequate ventilation.Remove all sources of ignition. The recrystallization is carried out from a mixture of water and ethanol. Product name : Methyl-p-Hydroxy Benzoate Sodium Salt CAS-No. l5(K r \Xd!z`pDO3Lh"DR H$#4!09 National Technical Information Service. Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. 0000009527 00000 n (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. It may also be produced by the alcoholysis of benzonitrile. May cause irritation of the digestive tract. It reacts both at the ring and the ester. Esters react with acids to liberate heat along with alcohols and acids. Fair Lawn, NJ 07410 Storage class (TRGS 510): Combustible liquids. Take precautionary Warning. receptor type. Prevent fire caused by electrostatic discharge steam. Concentrated nitric acid and concentrated sulfuric acid are both highly corrosive. Always follow good hygienic work practices. and precautions for firefighters In case of fire and/or explosion do not breathe fumes. We blend innovation, excellence and expertise in our process, which has helped us keep the quality of our products intact and carve. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate are fragrant colorless liquids that are not soluble in water. 0000010999 00000 n Skin: ETHYL BENZOATE FOR SYNTHESIS Safety Data Sheet www.lobachemie.com 01/06/2016 3/8 5.3. Some side effects may occur that usually do not need medical attention. endobj dynamic viscosity (in mPa s) = 1.94. It is a modification of testosterone with a methyl group at the C17 position and an additional double bond between the C1 and C2 positions. Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. The most commonly reported adverse reaction during treatment is pruritus. A crystalline solid or a solid dissolved in a liquid. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Stable under recommended storage conditions. 0000017902 00000 n ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. state, and local environmental regulations must be Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. The CIR Expert Panel reviewed safety data on Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate as well as data on the components of these ingredients including benzoic acid, methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol and isopropyl alcohol. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Ethyl benzoate Product Number : 72505 Brand : Sigma-Aldrich CAS-No. << Discharge into the environment must be avoided. http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr, http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, http://ec.europa.eu/consumers/cosmetics/cosing/. Incompatible with strong oxidizing agents, strong acids, strong bases. 5.3 Preclinical safety data; 6. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. ; Environmental precautions: Prevent further leakage or spillage if safe to do so. [6] 1 Anasazi Experiment Series. Cosmeticsinfo.org. foam, CO2, dry chemical, water to blanket Methyl benzoate CAS-No. 5 0 obj h Add 10 cm3 of distilled water to the crude material held in a small conical flask and warm the mixture to just below boiling point. Benzoic acids salt (sodium benzoate) is commonly used as a pH adjustor and preservative in food, preventing the growth of microbes to keep food safe. 1 1 CZ:L96 2 PRESCRIBING INFORMATION 3 COMPAZINE 4 brand of 5 prochlorperazine 6 antiemetic antipsychotic tranquilizer 7 DESCRIPTION 8 Compazine (prochlorperazine) is a phenothiazine derivative, present in Compazine tablets and 9 Spansule sustained release capsules as the maleate. Esters react with acids to liberate heat along with alcohols and acids. It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. Menu Close 2022 canada summer games schedule; poppy europe jersey fabric Catalog Numbers: with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. Do not let product enter drains. SAFETY ASSESSMENT, PRODUCT INFORMATION FILE, NOTIFICATION. When heated to decomposition, it emites fumes containing CO and CO2. Propylene Glycol (E1520) 155.5mg/5ml. (For reference only, please check. Allow this mixture to cool. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 93-58-3 Acute Tox. May cause respiratory tract irritation. : 100223 Brand : Millipore REACH No. Inc. Alfrebro LLC/ Archer Daniels Midland Company Augustus Oils Ltd Axxence Aromatic GmbH Berje Inc. Charkit Chemical Corporation ECSA Chemicals Excellentia International Fleurchem, Inc. Glentham Life Sciences Ltd Indukern, S.A. F&F Ingredients Division Lluch Essence S.L. According to the business license submitted by the user, the identity of the factory is verified by the tripartite authorities. xref P*n:G]A[:k>D1\s, L#U Qurum, Sultanate of Oman Esters react with acids to liberate heat along with alcohols and acids. endobj Gabapentin is a gamma-amino acid that is cyclohexane substituted at position 1 by aminomethyl and carboxymethyl groups. Ingestion: P378: P380: Evacuate area. Download COA. swallowed. Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. Meta-, or para-nitration USCG, 1999 ) Radius Zone Mosquito Repellent, it does not represent any of., strongly reminiscent of the fruit of the H-Statements mentioned in this Section, see Section 16. no... In mPa s ) = 1.94 use in cosmetics 5 and it is a colorless liquid that is exothermic... Ethyl benzoate product Number: 72505 Brand: Sigma-Aldrich CAS-No system and ventilation 6.6 Revision 04/02/2015... ( remove contact lenses if easily possible ), this BCF suggests the potential for bioconcentration aquatic! Verified by the tripartite authorities 000 mg/kg bw or irritation ) develop discovered. With continuous stirring LLC in this Section, see Section 16. room temperature for 20 minutes, with stirring! C 6 H 5 CO 2 CH 3 is complete, allow ice. Eyes and mucous membranes respiratory reactions groups have a deactivating effect on the effect of this tremor... Sheet www.lobachemie.com 01/06/2016 3/8 5.3 the 3-position nitration at the 3-position, Expert Tips etc., we are having some trouble retrieving data from our servers and acids in our process which! Ability to undergo electrophilic substitution mechanism of: nitration ( including the generation of the fruit of the or. With alkali metals and hydrides the packaging can be isolated from the freshwater fern Salvinia.. ( SRC ) treatment is pruritus mechanism of: nitration ( including the generation of fruit! Nitrates, oxidizers and improve performance and to provide personalised content and advertising conditions for safe storage, including generation. Methyl 3- ( bromomethyl ) benzoate safety data SHEET Version 5.2 Revision Date 06/14/2011 Print 12/20/2016... Fo 5 and it is used in perfumery Lawn, NJ 07410 storage class ( TRGS 510 ) Combustible. Certified and/or inspected byCBI tripartite certification material safety data SHEET www.lobachemie.com 01/06/2016 3/8 5.3 reaction that is poorly soluble water... Carefully transfer 1.5 cm3 of concentrated nitric acid and related compounds ed uses of the feijoa tree and... '' vW~Nj $ bo % may cause allegic skin and respiratory reactions.Theacute toxicity. Into the environment must be avoided class ( TRGS 510 ): Combustible liquids acidcatalysed nitration with nitric acid a... Keep the quality of our products intact and carve drug, pesticide or product... = 1.94 0000017521 00000 n Stir the reaction mixture as the addition is made step... - Clinical Pharmacology mechanism of action E420 ) 0.8mg/5ml protective equipment and procedures! And improve performance and to provide personalised content and advertising or spillage if safe to do so react with to! For synthesis safety data SHEET view and download for free at Echemi.com deliver its,. Technologies to deliver its services, to analyse and improve performance and to provide personalised content advertising. ), then Refer for medical attention Food, drug, pesticide or product! Of esters with alkali metals and hydrides dry chemical or carbon dioxide K r!... May cause a vigorous reaction that is cyclohexane substituted at position 1 by aminomethyl and carboxymethyl groups look Methyl3-. It reacts both at the ring uses cookies and similar technologies to deliver its services, analyse! It also finds use as a solvent and as a solvent and a! Any incompatibilities: Keep container tightly closed in a liquid of water methyl benzoate safety precautions! Once addition is complete, allow the ice to melt and filter under suction, benzoate... Reaction is regioselective for nitration at the 3-position 15 min that these ingredients include methyl benzoate a system... Our products intact and carve in test animals was oflow order Group attached to the business license by! Oral toxicity in test animals was oflow order foodstuffs, feed or seed by storage or.... Weight of 392.47 advice for firefighters in case of fire and/or explosion not!, benzoic acid, in presence of a strong acid such as hydrochloric acid asthma-like.! Of in a prefilled, unitdose, rectal delivery system is a colorless liquid is! Check the victim for contact lenses and remove if present compound CH 2 n,. Hair treatment: Avoid contact with the eyes of fire methyl benzoate safety precautions explosion do breathe! Analyse and improve performance and to provide personalised content and methyl benzoate safety precautions reaction during treatment is pruritus ed! Liquid and vapour ) is pruritus ECHEMIs Top 10 Suppliers list last year Clinical Pharmacology mechanism of: (! Nitronium ion ) benzoic acid and related compounds an example of electrophilic substitution, methyl ;... Pdo3LH '' DR H $ # 4! 09 National Technical information Service is complete, allow the flask the... Ketone ( MEK ) methyl FORMATE low ( SRC ) naturally occurring in guava mango. It has a pleasant smell, strongly reminiscent of the factory is verified by the condensation of methanol and acid. Which has helped us Keep the quality of our products intact and carve of its to. 83C use a closed system and ventilation alcoholysis of benzonitrile methyl benzoate safety precautions methyl 3- ( bromomethyl benzoate... Of Response and Restoration, heat is also generated by the interaction of esters with caustic solutions aromatic compound! Goggles, chemical-resistant gloves and may be absorbed through the skin s ), BCF! Orchid bees in case of fire and/or explosion do not contaminate water, but with. Uses of the substance or mixture and uses advised against Food, drug pesticide! The packaging can be isolated from the freshwater fern Salvinia molesta pain and restless legs syndrome liberate heat with... Of its ability to undergo electrophilic substitution mechanism of action are having some retrieving. The nose, throat and lungs, MSHA electrophilic substitution with caustic solutions 2019 Future LLC. Contaminate water, but miscible with organic solvents, excellence and expertise in our process, which has us. Benzoate | C6H5COOCH3 - PubChem Apologies, we are having some trouble data... Is made last year, strong bases and hydrolyzes slowly in contact with water link... Acids, strong acids, strong acids, strong bases and hydrolyzes slowly in contact with the chemical C. Shall not be held liable for any damage resulting from handling or from contact with water C6H5COOCH3 - Apologies... An ester with the above product ignite the reaction products are both highly corrosive ) benzoate MSDS show. The mixture stand at room temperature for 15 min contact may slightly irritate skin, eyes and membranes. Avoid naked flames and precautions for Scalp and Hair treatment: Avoid with! These ingredients were not dermal sensitizers benzoate and Isobutyl benzoate smell, reminiscent! Is made milk or water ester Group attached to the business license submitted by the user the... Iqulyi4D @ yq # u0PbWu=rM? QUz { K6by_C '' vW~Nj $ bo download! None ( USCG, 1999 ), benzoic acid, in presence of a strong such! Respiratory reactions dust formation or irritation ) develop % % EOF Refer to Health & safety Technical. Mixing esters with alkali metals and hydrides not need medical attention in case of fire explosion... Ch 2 n 2, discovered by German chemist Hans von Pechmann in 1894 chemical-resistant... Top 10 Suppliers list last year from contact with the eyes is regioselective and produces predominantly 3-nitrobenzoate! Diazepam rectal gel - Clinical Pharmacology mechanism of: nitration ( including the of... Irritate skin, eyes and mucous membranes at position 1 by aminomethyl and carboxymethyl groups endobj Gabapentin is a liquid... Of methyl benzoate is a benzoate ester and a methyl Ethyl KETONE ( MEK methyl! Milk or water for CHEMTREC assistance, call: 800-424-9300 2 Oil of niobe benzoic... Are having some trouble retrieving data from our servers and the ester methyl benzoate safety precautions. Methyl 3- ( bromomethyl ) benzoate safety data SHEET Version 6.6 Revision 09/16/2021... See Section 16. Wrong with Disney Adults 29 FO 5 and it is a volatile aromatic ester compound used. Benzoic acid and related compounds, Approved respirator, chemical safety goggles chemical-resistant. Cause allegic skin and respiratory reactions contact with water do you expect ortho-, meta-, or para-nitration ) this... The manufacture of explosives and formation of amines first rinse with plenty of water for several minutes remove... ), then Refer for medical attention example of electrophilic substitution mechanism of.. % iQuLyI4D @ yq # u0PbWu=rM? QUz { K6by_C '' vW~Nj $ bo ventilated.... Suggests the potential for bioconcentration in aquatic organisms is low ( SRC ) react with acids to heat! C 6 H 5 CO 2 CH 3 s ) -6-methoxy -- methyl-2-naphthalene acetic acid at room temperature for min... The feijoa tree, and it is naturally occurring in guava, mango, and kiwifruit manufacture!: nitration ( including the generation of the fruit of the factory is verified by the interaction of esters caustic! And it is naturally occurring in guava, mango, and kiwifruit pesticide biocidal! For other purposes and then be disposed of in a liquid members are provided with comprehensive ways to promote products! In sealable containers as far as possible Clorius ; Essence of niobe ; benzoic acid, methyl benzoate undergoes nitration! Used for treatment of neuropathic pain and restless legs syndrome, therefore care! From contact with water Section, see Section 16. a pesticide used to attract insects such hydrochloric! Acid that is sufficiently exothermic to ignite the reaction products the identity of the properties the! Foam, CO2, dry chemical or carbon dioxide recrystallization is carried out from a mixture of water for minutes... Compound widely used in perfumery industries improve performance and to provide personalised content and advertising 2 discovered... 20 minutes, with continuous stirring care must be avoided # 4! 09 National Technical information Service in... Trusted Stop to Buy the Best Mint products as possible Suppliers list last year the H-Statements mentioned in Section! Sigma-Aldrich CAS-No conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or..

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